COMPUTER-GUIDED TOTAL SYNTHESIS OF NATURAL PRODUCTS. RECENT EXAMPLES AND FUTURE PERSPECTIVES

Franco Della-Felice, Ronaldo A. Pilli, Ariel M. Sarotti.

J. Braz. Chem. Soc. 2018, 29, 1041-1075

CATALYTIC ASYMMETRIC SYNTHESIS AND STEREOCHEMICAL REVISION OF (+)-CRYPTOCONCATONE H

Franco Della-Felice, Ariel M. Sarotti, Ronaldo A. Pilli

J. Org. Chem., 2017, 82, 9191–9197

Preferential Mitochondrial Localization of a Goniothalamin Fluorescent Derivative

Ismael Raitz, Roberto Y. de Souza Filho, Lorena P. de Andrade, Jose R. Correa, Brenno A. D. Neto, Ronaldo A. Pilli

ACS Omega, 2017, 2, 3774–3784

The Nobel Prize in Chemistry 2016: Molecular Machines

Karla S. Feu, Francisco F. de Assis , Siddavatam Nagendra, Ronaldo A. Pilli

Quim. Nova 2017, 40, 113-123

Total Synthesis of Natural Dihydropyranones: A Contribution to the Structural Elucidation of Natural Products. Coibacins A and B, Cryptomoscatones D1, D2 and E3

Ronaldo Aloise Pilli, Luiz Fernando Toneto Novaes, Vânia Maria Teixeira Carneiro, Roberta Lopes Drekener and Carolina Martins Avila.

Current Organic Synthesis 2015, 12, 523-529

Anti-inflammatory and antinociceptive effects of racemic goniothalamin, a styryl lactone

Débora Barbosa Vendramini-Costa, Humberto Moreira Spindola, Glaucia Coelho de Mello, Edson Antunes, Ronaldo Aloise Pilli, João Ernesto de Carvalho

Life Sciences 2015, 139, 83–90

Crystal structures of the apo form and a complex of human LMW-PTP with a phosphonic acid provide new evidence of a secondary site potentially related to the anchorage of natural substrates

Emanuella M.B. Fonseca, Daniela B.B. Trivella, Valéria Scorsato, Mariana P. Dias, Natália L. Bazzo, Kishore R. Mandapati, Fábio L. de Oliveira, Carmen V. Ferreira-Halder, Ronaldo A. Pilli, Paulo C.M.L. Miranda, Ricardo Aparicio

Bioorg. Med: Chem. 2015, 23, 4462–4471 

Cascade cyclization triggered by imine formation. Formal synthesis of the alkaloid (±)-stemoamide and its 9a-epimer

Gilmar A. Brito, Ariel M. Sarotti, Peter Wipf, Ronaldo A. Pilli

Tetrahedron Lett. 2015, 48, 6664-6668

Total Synthesis and Tentative Structural Elucidation of Cryptomoscatone E3: Interplay of Experimental and Computational Studies

Luiz F. T. Novaes, Ariel M. Sarotti, Ronaldo A. Pilli

J. Org. Chem., 2015, 80 (24), pp 12027–1203

Total synthesis and stereochemical assignment of cryptolatifolione

Luiz F. T. Novaes, Ariel M. Sarotti, Ronaldo A. Pilli

RSC Adv. 2015, 5, 53471-53476

Enantioselective Total Synthesis of (+)-Lyngbyabellin M

Rodrigo V. Pirovani, Gilmar A. Brito, Rosimeire C. Barcelos, Ronaldo A. Pilli

Mar. Drugs 2015, 13, 3309-3324

Is RK-682 a promiscuous enzyme inhibitor? Synthesis and in vitro evaluation of protein tyrosine phosphatase inhibition of racemic RK-682 and analogues

Vânia M. T. Carneiro, Daniela B. B. Trivella, Valéria Scorsato, Viviane L. Beraldo, Mariana P. Dias, Tiago J. P. Sobreira, Ricardo Aparicio, Ronaldo A. Pilli

Eur. J. Med. Chem. 2015, 97, 42-54

(−)-Tarchonanthuslactone Exerts a Blood Glucose-Increasing Effect in Experimental Type 2 Diabetes Mellitus

Gabriela F. P. de Souza, Luiz F. T. Novaes, Carolina M. Avila, Lucas F. R. Nascimento, Licio A. Velloso and Ronaldo A. Pilli

Molecules, 2015, 20, 5038-5049

Gastroprotective effects of goniothalamin against ethanol and indomethacin-induced gastric lesions in rats: Role of prostaglandins, nitric oxide and sulfhydryl compounds

Débora B. Vendramini-Costa, Karin M. Monteiro, Leilane H. Iwamoto, Michelle P. Jorgeb, Sirlene V. Tinti, Ronaldo A. Pilli, João E. de Carvalho

Chemico-Biological Interactions 2014, 224, 206-212

Design and Synthesis of N-Acylated Aza-Goniothalamin Derivatives and Evaluation of Their in vitro and in vivo Antitumor Activity

Rosimeire C. Barcelos, Julio C. Pastre, Débora B. Vendramini-Costa, Vanessa Caixeta, Giovanna B. Longato, Paula A. Monteiro, João E. de Carvalho, Ronaldo A. Pilli

ChemMedChem 2014, 9, 2725-2743

A new goniothalamin N-acylated aza-derivative strongly downregulates mediators of signaling transduction associated with pancreatic cancer aggressiveness

Rosimeire C. Barcelos, Karin J. Pelizzaro-Rocha, Julio C. Pastre, Marina P. Dias, Carmen V. Ferreira-Halder, Ronaldo A. Pilli

Eur. J. Med. Chem. 2014, 87, 745-758

Total synthesis of cryptomoscatones D1 and D2: stereochemical assignment of cryptomoscatone D1

Luiz F. T. Novaes, Roberta L. Drekener, Carolina M. Avila, Ronaldo A. Pilli

Tetrahedron, 2014, 70, 6467-6473

COIBACINS A AND B: TOTAL SYNTHESIS AND STEREOCHEMICAL REVISION

Vânia M. T. Carneiro, Carolina M. Avila, Marcy, J. Balunas, William H. Gerwick, Ronaldo A. Pilli

J. Org. Chem. 2014, 79, 630-642

ONE-POT SYNTHESIS OF ORGANOPHOSPHATE MONOESTERS FROM ALCOHOLS

Lucas M. Lira, Dimitar Vasilev, Ronaldo A. Pilli, Ludger A. Wessjohann

Tetrahedron Lett. 2013, 54, 1690-1692

(+)-ALTHOLACTONE EXHIBITS BROAD SPECTRUM IMMUNE MODULATING ACTIVITY BY INHIBITING THE ACTIVATION OF PRO-INFLAMMATORY CYTOKINES IN RAW 264.7 CELL LINES

Tyler A. Johnson, Johann Sohn, Aidan E. Ward, Tanya L. Cohen, Nicholas D. Lorig-Roach, Haixia Chen, Ronaldo A. Pilli, Elizabeth A. Widjaja, Muhammad Hanafi, Leonardus B.S. Kardono, Puspa D. Lotulung, Kyria Boundy-Mills, Leonard F. Bjeldanes

Bioorg. Med. Chem. 2013, 21, 4358-4364

DESIGN, SYNTHESIS AND IN VITRO EVALUATION AGAINST HUMAN CANCER CELLS OF 5-METHYL-5-STYRYL-2,5-DIHYDROFURAN-2-ONES, A NEW SERIES OF GONIOTHALAMIN ANALOGUES

Marjorie Bruder, Débora B. Vendramini-Costa, João E. de Carvalho, Ronaldo A. Pilli

Bioorg. Med. Chem. 2013, 21, 5107-5117

SYNTHESIS OF METHOXYLATED GONIOTHALAMIN, AZA-GONIOTHALAMIN AND GAMMA-PYRONES AND THEIR IN VIVO EVALUATION AGAINST CANCER cells

Rosimeire C. Barcelos, Julio C. Pastre, Vanessa Caixeta, Débora B. Vendramini-Costa, João E. de Carvalho, Ronaldo A. Pilli

Bioorg. Med. Chem. 2012, 20, 3635-3651

The antinociceptive activity of harmicine on chemical-induced neurogenic and inflammatory pain models in mice

Humberto M. Spindola, Débora B. Vendramini-Costa, Manoel T. Rodrigues Jr., Mary A. Foglio, Ronaldo A. Pilli, João E. de Carvalho

Pharmacol. Biochem. Be. 2012, 102, 133-138

Knocking Down Low Molecular Weight Protein Tyrosine Phosphatase (LMW-PTP) Reverts Chemoresistance through Inactivation of Src and Bcr-Abl Proteins

Paula A. Ferreira, Roberta R. Ruela-de-Sousa, Karla C. S. Queiroz, Ana C. S. Souza, Renato Milani, Ronaldo A. Pilli, Maikel P. Peppelenbosch, Jeroen den Hertog, Carmen V. Ferreira

Plos One 2012, 7, e44312

NMR studies of inclusion complexation of the pyrrolizidine alkaloid retronecine and p-sulfonic acid calix[6]arene

Daniel L. da Silva, Eder C. Tavares, Leila S. Conegero, Ângelo de Fátima, Ronaldo A. Pilli, Sergio A. Fernandes

J. Incl. Phenom. Macro. Chem. 2011, 69, 149-155

Effect of goniothalamin on the development of Ehrlich solid tumor in mice

Débora B. Vendramini-Costa, Ilton B. D. de Castro, Ana L. T. G. Ruiz, Cilene Marquissolo, Ronaldo A. Pilli, João E. de Carvalho

Bioorg. Med. Chem. 2010, 18, 6742-6747

The chemistry of Stemona alkaloids: An update

Ronaldo A. Pilli, Giovanni B. Rosso, Maria C. F. de Oliveira

Nat. Prod. Rep. 2010, 27, 1908-1937

THE SYNTHESES OF THE MARINE METABOLITES 3-BROMOVERONGIAQUINOL AND 5-MONOBROMOCAVERNICOLIN

Luiz A. F. de Godoy, Ronaldo A. Pilli

Quím. Nova 2010, 33, 2042-2045

Novel Supramolecular Palladium Catalyst for the Asymmetric Reduction of Imines in Aqueous Media

Wender A da Silva, Manoel T. Rodrigues, N. Shankaraiah, Renan B. Ferreira, Carlos K. Z. Andrade, Ronaldo A. Pilli, Leonardo S. Santos

Org. Lett. 2009, 11, 3238-3241

Asymmetric total synthesis and antiproliferative activity of goniothalamin oxide isomers

Cilene Marquissolo, Ângelo de Fátima, Luciana K. Kohn, Ana L. T. G. Ruiz, João E. de Carvalho, Ronaldo A. Pilli

Bioog. Chem. 2009, 37, 52-56

Antiproliferative activity of arborescidine alkaloids and derivatives

Leonardo S. Santos, Cristina Theoduloz, Ronaldo A. Pilli, Jaime Rodriguez

Eur. J. Med. Chem. 2009, 44, 3810-3815

The Asymmetric Total Synthesis of (+)- and (-)-Trypargine via Noyori Asymmetric Transfer Hydrogenation

Ronaldo A. Pilli, Manoel T. Rodrigues Jr.

J. Braz. Chem. Soc. 2009, 20, 1434-1440

In vitro studies of anticandidal activity of goniothalamin enantiomers

C. V. B. Martins, M. A. de Resende, D. L. da Silva, T. F. F. Magalhães, L. V. Modolo, Ronaldo A. Pilli, Ângelo de Fátima

J. Appl. Microbiol. 2009, 107, 1279-1286

Fifteen years of biological and synthetic studies of decarestrictine family

Valéria B. Riatto, Ronaldo A. Pilli, Mauricio M. Victor

Tetrahedron 2008, 64, 2279-2300

Antifungal Activities of Goniothalamin Enantiomers

Ângelo de Fátima, Cleide V. B. Martins, Maria A. de Resende, Thais F. F. Magalhães, Bruno H. S. Lima, Gisele A. Watanabe, Ana L. T. G. Ruiz, João E. de Carvalho, Ronaldo A. Pilli

Lett. Drug Des. Discov. 2008, 5, 74-78

Stereoselective addition of chiral titanium enolates to 5-substituted five-membered oxocarbenium ions

Ronaldo A. Pilli, Valéria B. Riatto

J. Braz. Chem. Soc. 2008, 19, 583-599

Stereoselective syntheses of (+)-isoretronecanol and (+)-5-epi-tashiromine via addition of chiral titanium (IV) enolates to cyclic N-acyliminium ions

Elaine Pereira, Conceição F. Alves, Maria A. Böckelmann, Ronaldo A. Pilli

Quím. Nova 2008, 31, 771-775

Enantioselective total syntheses of ropivacaine and its analogues

Nagula Shankaraiah, Ronaldo A. Pilli, Leonardo S. Santos

Tetrahedron Lett. 2008, 49, 5098-5100

Cytotoxicity of goniothalamin enantiomers in renal cancer cells: Involvement of nitric oxide, apoptosis and autophagy

Ângelo de Fátima, Willian F. Zambuzzi, Luzia Modolo, Christiane A. B. Tarsitano, Fernanda R. Gadelha, Stephen Hyslop, João E. de Carvalho, Ione Salgado, Carmen V. Ferreira, Ronaldo A. Pilli

Chem. Biol. Interact. 2008, 176, 143-150

Adsorption kinetic and properties of self-assembled monolayer based on mono(6-deoxy-6-mercapto)-β-cyclodextrin molecules

Flavio S. Damos, Rita C. S. Luz, Adão A. Sabino, Marcos N. Eberlin, Ronaldo A. Pilli, Lauro T. Kubota

J. Electroanal. Chem. 2007, 601, 181-193

The Mechanism of the Stille Reaction Investigated by Electrospray Ionization Mass Spectrometry

Leonardo S. Santos, Giovanni B. Rosso, Ronaldo A. Pilli, Marcos N. Eberlin

J. Org. Chem. 2007, 72, 5809-5812

Cytotoxic activity of (S)-goniothalamin and analogues against human cancer cells

Ângelo de Fátima, Luciana K. Kohn, João E. de Carvalho, Ronaldo A. Pilli

Bioorg. Med. Chem. 2006, 14, 622-631

Diastereoselective addition of nitro compounds to α,β-unsaturated γ-butyrolactones

Giovanni B. Rosso, Ronaldo A. Pilli

Tetrahedron Lett. 2006, 47, 185-188

Addition of carbon nucleophiles to cyclic N-acyliminium and oxocarbenium ions under solvent-free conditions

Luiz A. F. de Godoy, Nilton S. Camilo, Ronaldo A. Pilli

Tetrahedron Lett. 2006, 47, 7853-7856

Synthesis and differential antiproliferative activity of Biginelli compounds against cancer cell lines: Monastrol, oxo-monastrol and oxygenated analogues

Dennis Russowsky, Rômulo F. S. Canto, Sergio A. A. Sanches, Marcelo . M. D'Oca, Ângelo de Fátima, Ronaldo A. Pilli, Luciana K. Kohn, Márcia A. Antônio, João E. de Carvalho

Bioorg. Chem. 2006, 34, 173-182

Transient intermediates of the Tebbe reagent intercepted and characterized by atmospheric pressure chemical ionization mass spectrometry

Eduardo C. Meurer, Lilian L. Rocha, Ronaldo A. Pilli, Marcos N. Eberlin, Leonardo S. Santos

Rapid Commun. Mass Spectrom. 2006, 20, 2626-2629

Alilação e Crotilação Catalítica e Enantiosseletiva de Aldeídos

Ângelo de Fátima, Luís G. Robello, Ronaldo A. Pilli

Quím. Nova 2006, 29, 1009-1026

Trypanocidal activity of 5,6-dihydropyran-2-ones against free trypomastigotes forms of Trypanosoma cruzi

Ângelo de Fátima, Cilene Marquissolo, Serio de Albuquerque, Ana A. Carraro-Abrahão, Ronaldo A. Pilli

Eur. J. Med. Chem. 2006, 41, 1210-1213

Styryl Lactones and Their Derivatives: Biological Activities, Mechanisms of Action and Potential Leads for Drug Design

Ângelo de Fátima, L. V. Modolo, Leila S. Conegero, Ronaldo A. Pilli, C. V. Ferreira, L. K. Kohn, João E. de Carvalho

Curr. Med. Chem. 2006, 13, 3371-3384

Asymmetric reduction of prochiral ketones using in situ generated oxazaborolidine derived from (1S,2S,3R,4R)-3-amino-7,7-dimethoxynorbornan-2-ol. An efficient synthesis of enantiopure (R)-tomoxetine

Alexandre A. M. Lapis, Ângelo de Fátima, José E. D. Martins, Valentim E. U. Costa, Ronaldo A. Pilli

Tetrahedron Lett. 2005, 46, 495-498

(R)-Goniothalamin: total syntheses and cytotoxic activity against cancer cell lines

Ângelo de Fátima, Luciana K. Kohn, Márcia A. Antônio, João E. de Carvalho, Ronaldo A. Pilli

Bioorg. Med. Chem. 2005, 13, 2927-2933

The stereoselective addition of titanium(IV) enolates of 1,3-oxazolidin-2-one and 1,3-thiazolidine-2-thione to cyclic N-acyliminium ion. The total synthesis of (+)-isoretronecanol

Elaine Pereira, Conceição F. Alves, Maria A. Böckelmann, Ronaldo A. Pilli

Tetrahedron Lett. 2005, 46, 2691-2693

A Concise Route to the Azaspirodecane Moiety of Halichlorine and Structurally Related Alkaloids

Andrea L. de Sousa, Ronaldo A. Pilli

Org. Lett. 2005, 7, 1617-1619

Sialic acids - From the comprehension of their involvement in biological processes to antiinfluenza drug design

Ângelo de Fátima, Lúcia H. B. Baptistella, Ronaldo A. Pilli, Luzia V. Modolo

Quím. Nova 2005, 28, 306-316

Zinc Triflate as Lewis Acid in Nucleophilic Addition to Cyclic N-Acyliminium Ions

Ronaldo A. Pilli, Luís G. Robello

Synlett 2005, 15, 2297-2300

Total Synthesis and Structural Elucidation of Natural Products: (-)-Delactonmycin, (+)-Plumerinine and (-)-Parvistemoamide

Ronaldo A. Pilli, Ivan R. Corrêa, Adriano O. Maldaner, Giovanni B. Rosso

Pure and Applied Chemistry 2005, 77, 1153-1160

A Concise Total Synthesis of (R)-Fluoxetine, a Potent and Selective Serotonin Reuptake Inhibitor

Ângelo de Fátima, Alexandre A. M. Lapis, Ronaldo A. Pilli

J. Braz. Chem. Soc. 2005, 16, 495-499

Enantioselective Total Syntheses of (+)-Arborescidine A, (−)-Arborescidine B, and (−)-Arborescidine C

Leonardo S. Santos, Ronaldo A. Pilli, Viresh H. Rawal

J. Org. Chem. 2004, 69, 1283-1289

The addition of carbon nucleophiles to cyclic N-acyliminium Ions in SDS/water

Nilton S. Camilo, Ronaldo A. Pilli

Tetrahedron Lett. 2004, 45, 2821-2823

Fast screening of low molecular weight compounds by thin-layer chromatography and "on-spot" MALDI-TOF mass spectrometry

Leonardo S. Santos, Renato Haddad, Nelci F. Höer, Ronaldo A. Pilli, Marcos N. Eberlin

Anal. Chem. 2004, 76, 2144-2147

Enantioselective syntheses of (R)- and (S)-argentilactone and their cytotoxic activities against cancer cell lines

Ângelo de Fátima, Luciana K. Kohn, Márcia A. Antônio, João E. de Carvalho, Ronaldo A. Pilli

Bioorg. Med. Chem. 2004, 12, 5437-5442

A Stereoselective Entry to Tetrasubstituted Quinolizidines and the Puzzling Structural Assignement of the Lupin Alkaloid Plumerinine

Adriano O. Maldaner, Ronaldo A. Pilli

Synlett 2004, 8, 1343-1346

Palladium-catalyzed double Cross-Coupling of E-Vinylic Dibromides with PhZnCl and the Synthesis of Tamoxifen

Ronaldo A. Pilli, Luís G. Robello

J. Braz. Chem. Soc. 2004, 15, 938-944

Probing the Mechanism of the Petasis Olefination Reaction by Atmospheric Pressure Chemical Ionization Mass and Tandem Spectrometry

Eduardo C. Meurer, Leonardo S. Santos, Ronaldo A. Pilli, Marcos N. Eberlin

Org. Lett. 2003, 5, 1391-1394

Reações Aldólicas Assimétricas e Catalíticas

Ivan R. Corrêa Jr., Ronaldo A. Pilli

Quím. Nova 2003, 26, 531-541

Total Synthesis and Structural Elucidation of (-)-Delactonmycin

Ivan R. Corrêa Jr., Ronaldo A. Pilli

Angew. Chem. Int. Ed. 2003, 42, 3017-3020

A novel asymmetric reduction of dihydro-beta-carboline derivatives using calix[6]arene/ chiral amine as host complex

Leonardo S. Santos, Sergio A. Fernandes, Ronaldo A. Pilli, Anita J. Marsaioli

Tetrahedron: Asymmetry 2003, 14, 2515-2519

Enantioselective Approach to the Asymmetric Synthesis of (6R)-hydroxymethyl-5,6-dihydro-2H-pyran-2-one. A Formal Synthesis of (R)-Argentilactone and Total Synthesis of (R)-Goniothalamin

Ângelo de Fátima, Ronaldo A. Pilli

ARKIVOC 2003, 118-126

Total Syntheses of (R)-Argentilactone and (R)-goniothalamin via Catalytic Enantioselective Allylation of Aldehydes

Ângelo de Fátima, Ronaldo A. Pilli

Tetrahedron Lett. 2003, 44, 8721-8724

Studies Toward the Construction of Alkylidene Quinolizidines. The Total Synthesis of Homopumiliotoxin 223G

Leonardo S. Santos, Ronaldo A. Pilli

J. Braz. Chem. Soc. 2003, 14, 982-993

The Intramolecular Heck Reaction and the Synthesis of Indolizidinone, Quinolizidinone and Benzoazepinone Derivatives

Leonardo S. Santos, Ronaldo A. Pilli

Synthesis 2002, 1, 87-93

Total Synthesis of (+)-Herbarumin I via Intermolecular Nozaki-Hiyama-Kishi Reaction

Adão A. Sabino, Ronaldo A. Pilli

Tetrahedron Lett. 2002, 43, 2819-2821

Stereoselectivity in the Intramolecular Nozaki-Hiyama-Kishi Reaction: Influence of the Substitution Pattern and Protecting Groups in the Construction of 10-Membered Lactones

Ronaldo A. Pilli, Mauricio M. Victor

Tetrahedron Lett. 2002, 43, 2815-2818

Mannich-type Reactions in Gas Phase: The Addition of Enol Silanes to Cyclic N-Acyliminium Ions

Daniela M. Tomazela, Luiz A. B. Moraes, Ronaldo A. Pilli, Marcos N. Eberlin, Marcelo G. M. D'Oca

J. Org. Chem. 2002, 67, 4652-4658

Synthesis of 1-Ferrocenyl-2-aryl(heteroaryl)acetylenes and 2-Ferrocenylindole Derivatives via the Sonogashira-Heck-Cassar Reaction

José C. Torres, Ronaldo A. Pilli, Maria D. Vargas, Flávio A. Violante, Simon J. Garden, Angelo C. Pinto

Tetrahedron 2002, 58, 4487-4492

Regio- and Diastereoselective Synthesis of 5-trans-substituted and 5,5-Disubstituted 2-Pyrrolidinones Derived from (S)-Malic Acid

Cristina M. Schuch, Ronaldo A. Pilli

Tetrahedron: Asymmetry 2002, 13, 1973-1980

The Addition of Allyltrimethylsilane to Cyclic N-Acyliminium Ions Derived from (S)-(+)-Mandelic Acid and Cyclohexyl-based Chiral

Marcelo G. M. D'Oca, Ronaldo A. Pilli, Vera L. Pardini, Denise Curi, Francisco C. M. Comninos

J. Braz. Chem. Soc. 2001, 12, 507-513

INTRINSIC GAS-PHASE ELECTROPHILIC REACTIVITY OF CYCLIC N-ALKYL- AND N-ACYLIMINIUM IONS

Marcelo G. M. D'Oca, Luiz A. B. Moraes, Ronaldo A. Pilli, Marcos N. Eberlin

J. Org. Chem. 2001, 66, 3854-3864

The Stereochemistry of the Nozaki-Hiyama-Kishi Reaction and the Construction of 10-Membered Lactones. The Enantioselective Total Synthesis of (-)-Decarestrictine D

Ronaldo A. Pilli, Mauricio M. Victor

J. Braz. Chem. Soc. 2001, 12, 373-385

Diastereoselection of the Addition of Silyloxyfurans to 5-, 6- and 7-Membered N-Acyliminium Ions

Maria C. F. de Oliveira, Leonardo S. Santos, Ronaldo A. Pilli

Tetrahedron Lett. 2001, 42, 6995-6997

Total Synthesis of (+/-)-Homopumiliotoxin 223G

Leonardo S. Santos, Ronaldo A. Pilli

Tetrahedron Lett. 2001, 42, 6999-7001

A Short Synthesis of (1S, 8aR)-1-Aminomethyl Indolizidine. The Heterocyclic Core of Stelletamides

Ronaldo A. Pilli, Paulo R. Zanotto, Maria A. Böckelmann

Tetrahedron Lett. 2001, 42, 7003-7005

Enhanced trans Diastereoselection in the Allylation of Cyclic Chiral N-Acyliminium Ions. Synthesis of Hydroxylated Indolizidines

Clécio F. Klitzke, Ronaldo A. Pilli

Tetrahedron Lett. 2001, 42, 5605-5608

Catálise Assimétrica e o Prêmio Nobel de Química de 2001. Novos Paradigmas e Aplicações Práticas

Ronaldo A. Pilli

Química Nova na Escola, 2001, 14, 16-24

RECENT PROGRESS IN THE CHEMISTRY OF THE STEMONA ALKALOIDS

Ronaldo A. Pilli, Maria C. F. de Oliveira

Nat. Prod. Rep. 2000, 17, 117-127

STEREOSELECTIVE SYNTHESIS OF FUNCTIONALIZED TRANS-2,5-DISUBSTITUTED TETRAHYDROFURANS

Ronaldo A. Pilli, Valéria B. Riatto, Ivo Vencato

Org. Lett. 2000, 2, 53-56

CREATION OF QUATERNARY STEREOCENTERS BY THE ADDITION OF ALLYLTRIBUTYLTIN TO CHIRAL CYCLIC N-ACYLIMINIUM IONS

Cristina M. Schuch, Ronaldo A. Pilli

Tetrahedron: Asymmetry 2000, 11, 753-764

FIRST TOTAL SYNTHESIS OF ASPINOLIDE B, A NEW PENTAKETIDE PRODUCED BY ASPERGILLUS OCHRACEUS

Ronaldo A. Pilli, Mauricio M. Victor, Armin de Meijere

J. Org. Chem. 2000, 65, 5910-5916

ADDITION OF CARBON NUCLEOPHILES TO SUBSTITUTED N-ACYLIMINIUM IONS. A STEREOSELECTIVE ROUTE TO TRANS-FUSED DECAHYDROQUINOLINE SYSTEMS

Adriano O. Maldaner, Ronaldo A. Pilli

Tetrahedron Lett. 2000, 41, 7843-7846

Diastereoselective Synthesis of 2,5-Disubstituted Tetrahydrofuran Derivatives

Ronaldo A. Pilli, Valéria B. Riatto

Tetrahedron: Asymmetry 2000, 11, 3675-3686

The Addition of 2-tert-Butyldimethylsilyloxyfuran to Chiral Cyclic N-Acyliminium Ions Containing Cyclohexyl-Based Chiral Auxiliaries

Marcelo G. M. D'Oca, Ronaldo A. Pilli, Ivo Vencato

Tetrahedron Lett. 2000, 41, 9709-9712

Addition of silylated carbon nucleophiles to iminium and cyclic N-acyliminium ions promoted by InCl3

Dennis Russowsky, Rogério Z. Petersen, Marla N. Godoi, Ronaldo A. Pilli

Tetrahedron Lett. 2000, 41, 9939-9942

THE RELATIVE CONFIGURATION OF A DELTA-LACTONE ISOLATED FROM THE MANDIBULAR GLAND SECRETION OF CALOMYRMEX SP MALES

Ronaldo A. Pilli, Maria A. Böckelmann, Andre Del Corso

J. Chem. Ecol. 1999, 25, 355-368

MICROBIAL SCREENING FOR THE ENANTIOSPECIFIC PRODUCTION OF ALKYL ESTERS OF 4-CHLORO-3-HYDROXYBUTANOIC ACID

J. R. Cagnon, Anita J. Marsaioli, V. B. Rialto, Ronaldo A. Pilli, G. P. Manflo, S. Y. Eguchi

Chemosphere, 1999, 38, 2243-2246

THE STEREOCHEMISTRY OF THE ADDITION OF TITANIUM ENOLATES OF N-PROPIONYL OXAZOLIDIN-2-ONES TO 5- AND 6-MEMBERED N-ACYLIMINIUM IONS

Ronaldo A. Pilli, Conceição F. Alves, Maria A. Böckelmann, Yvonne P. Mascarenhas, J. G. Nery, Ivo Vencato

Tetrahedron Lett. 1999, 40, 2891-2894

STEREOSELECTIVE ALKYLATION OF N-BOC-2-PYRROLIDINONES AND N-BOC-2-PIPERIDINONES. SYNTHESIS AND CHARACTERIZATION OF DISUBSTITUTED LACTAMS

Adriano O. Maldaner, Ronaldo A. Pilli

Tetrahedron, 1999, 55, 13321-13332

THE ASYMMETRIC SYNTHESIS OF (+)-SITOPHILURE, THE NATURAL FORM OF THE AGGREGATION PHEROMONE OF SITOPHILUS ORIZAE M. AND SITOPHILUS ZEAMAIS

Ronaldo A. Pilli, Valéria B. Riatto

J. Braz. Chem. Soc. 1999, 10, 363-368

LIMITATIONS IN DETERMINING ENANTIOMERIC EXCESS OF ALCOHOLS BY 31P-NMR OF THE PHOSPHONATE DERIVATIVES

Antonio Laverde Jr., Domingos S. de Miranda, Gelson J. A. da Conceição, Heiko Schirmer, Ronaldo A. Pilli, Armin de Meijere, Anita J. Marsaioli

J. Braz. Chem. Soc. 1999, 10, 293-298

TOTAL SYNTHESIS OF (-)-DECARESTRICTINE D THROUGH A STEREOSELECTIVE INTRAMOLECULAR NOZAKI-HIYAMA-KISHI REACTION

Ronaldo A. Pilli, Mauricio M. Victor

Tetrahedron Lett. 1998, 39, 4421-4424

TOTAL SYNTHESIS OF 10-DEOXYMETHYNOLIDE, THE AGLYCON OF THE MACROLIDE ANTIBIOTIC 10-DEOXYMETHYMYCIN

Ronaldo A. Pilli, Carlos K. Z. de Andrade, Carlos R. O. Souto, Armin de Meijere

J. Org. Chem. 1998, 63, 7811-7819

A CHEMOENZYMATIC SYNTHESIS OF THE SEX PHEROMONE OF LASIODERMA SERRICORNE F

Ronaldo A. Pilli, Valéria B. Riatto

J. Braz. Chem. Soc. 1998, 9, 571-576

The stereochemistry of the addition of carbon nucleophiles to imines and iminium ions

Ronaldo A. Pilli, Dennis Russowsky

Trends in Org. Chem. 1997, 6, 101-123

Addition of a Chiral Boron Enolate to Cyclic N-Acyliminium Ions. Stereocontrolled Synthesis of the Pyrrolizidine Ring System

Ronaldo A. Pilli, Denis Russowsky

J. Org. Chem. 1996, 61, 3187-3190

Synthesis and biological activities of N,N-dimethyl-2-propen-1-amine derivatives

R. de Conti, S. M. N. Gimenez, M. Haun, Ronaldo A. Pilli, S. L. de Castro, Nelson Durán

Eur. J. Med. Chem. 1996, 31, 915-918

An Efficient Total Sinthesis of a Synthetic Equivalent of the Prelog-Djerassi Lactonic Acid

Ronaldo A. Pilli, Carlos K. Z. de Andrade, Carlos R. O. Souto

J. Braz. Chem. Soc. 1996, 7, 279-283

A ONE-POT PREPARATION OF QUINOLIZIDIN-2-ONE AND INDOLIZIDIN-7-ONE RING SYSTEMS. CONCISE TOTAL SYNTHESES OF (+/-)-MYRTINE, (+/-)-LASUBINE II AND (-)-INDOLIZIDINE 223AB

Ronaldo A. Pilli, Luiz C. Dias, Adriano O. Maldaner

J. Org. Chem. 1995, 60, 717-722

Biosynthesis of a trypanocide by Chromobacterium violaceum

Nelson Durán, R. V. Antonio, M. Haun, Ronaldo A. Pilli

World J. Microb. Biot. 1994, 10, 686-690

A Short Formal Synthesis of (-)-Serricornine

Ronaldo A. Pilli, Carlos K. Z. de Andrade

Synth. Commun. 1994, 24, 233-241

Controle Estereoquímico e Síntese de Produtos Naturais, Feromônios, Alcalóides e Macrolídeos

Ronaldo A. Pilli

Quím. Nova 1994, 17, 159-166

STEREOSELECTIVE TOTAL SYNTHESIS OF (+/-)-INVICTOLIDE. AN EFFICIENT PREPARATION OF A TRISUBSTITUTED DELTA-LACTONE FROM ALDOL PRECURSORS

Ronaldo A. Pilli, Maria M. Murta

J. Org. Chem. 1993, 58, 338-342

Tandem N-acyliminium-Michael addition reaction. An efficient total Synthesis of the quinolizidine alkaloids (+/−)-myrtine and (+/−)-lasubine II

Ronaldo A. Pilli, Luiz C. Dias, Adriano O. Maldaner

Tetrahedron Lett. 1993, 34, 2729-2732

RESPOSTA OLFATIVA DE SITOPHILUS ZEAMAIS MOTSCH. (COLEOPTERA: CURCULIONIDAE) AO FEROMONIO SINTETICO DE AGREGACAO SITOFILURE

Ronaldo A. Pilli, Silvio Favero, L. O. Salgado, Evaldo F. Vilela

Anais da Sociedade Entomológica do Brasil, 1993, 22, 427

Degradation of Beta-O-4 lignin model and related compounds by the ascomyceteChrysonilia sitophila (TFB 27441 strain)

Raquel F. P. Nogueira, Ronaldo A. Pilli, Nelson Durán

Appl. Biochem. Biotechnol. 1992, 33, 169-176

MOLECULAR AND CRYSTAL STRUCTURE OF (2RS, 3RS)-2-METHYL-3-(p-CHLOROANILINE)-3-PHENYL-1-PROPIOFENONE

Ivo Vencato, Yvone P. Mascarenhas, Ronaldo A. Pilli, Dennis Russowsky

J. Braz. Chem. Soc. 1992, 3, 65-69

TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE (TMSOTF) CATALYSED AMIDOALKYLATION OF SILYLENOLETHERS. APPLICATION TO THE TOTAL SYNTHESIS OF (+/-)-SEDAMINE AND (+/-)-ALLOSEDAMINE

Ronaldo A. Pilli, Luiz C. Dias

Synth. Commun. 1991, 21, 2213-2229

STEREOSELECTIVE TOTAL SYNTHESIS OF SOME INSECT PHEROMONES:(+/-)-SERRICORNINE AND (+/-)-INVICTOLIDE

Ronaldo A. Pilli, Maria M. Murta

Mem. Inst. Oswaldo Cruz 1991, 86, 117-120

Molecular and Crystal Structure of (1SR, 3RS)-3-p-Chloro Anilino-1,3-Diphenyl-1-Propanol

Ivo Vencato, Yvonne P. Mascarenhas, Ronaldo A. Pilli, Luiz C. Dias

J. Braz. Chem. Soc. 1991, 2, 93-97

Total Synthesis of (4SR, 5RS)-5-Hydroxy-4-Methyl-3-Heptanone, the Racemic Form of the Aggregation Pheromone of S. orizae and S. zeamais

Ronaldo A. Pilli, Maria M. Murta, Denis Russowsky, Maria A. Boeckelmann

J. Braz. Chem. Soc. 1991, 2, 121-123

Diastereoselective reduction of acyclic N-aryl-beta-amino ketones

Ronaldo A. Pilli, Denis Russowsky, Luiz C. Dias

J. Chem. Soc. Perkin Trans. I, 1990, 1213-1214

Molecular and Crystal Structure of 2-Bromo-1-Hydroxy-1-Phenyl-4,4-Dimethyl-3-Pentanone

Ivo Vencato, Yvonne P. Mascarenhas, Ronaldo A. Pilli, Ney M. C. Grimaldi

J. Braz. Chem. Soc. 1990, 1, 59-62

Structure of 5-hydroxy-2,2-dimethyl-4-(p-toluenesulfonamido)-3-hexanone

Ivo Vencato, Yvonne P. Mascarenhas, Ronaldo A. Pilli, Maria I. H. Agostini

Acta Cryst. 1989, C45, 1174-1176

An Efficient and Stereoselective Total Synthesis of (+/-)-Serricornine

Ronaldo A. Pilli, Maria M. Murta

Synth. Commun. 1988, 18, 981-993

SECONDARY MANNICH BASES VIA TRIMETHYLSILYLTRIFLUOROMETHANESULFONATE PROMOTED ADDITION OF SILYLENOLETHERS TO SCHIFF BASES

Ronaldo A. Pilli, Denis Russowsky

J. Chem. Soc., Chem. Commun., 1987, 14, 1053-1054

Mass spectra of some 4(1H)-pyridazinone derivatives

Concetta Kascheres, Albert J. Kaschers, Ronaldo A. Pilli

Organic Mass Spectrometry, 1985, 20, 483-484

SIMPLE DIASTEREOSELECTION IN THE FORMATION OF ALFA,BETA-DIHYDROXYALDEHYDES: AN ALDOL APPROACH TO THE SYNTHESIS OF ERYTHRONOLIDE A

Clayton H. Heathcock, Steven D. Young, James P. Hagen, Ronaldo Pilli, Ulrich Badertscher

Chemica Scripta, 1985, 25, 39

Acyclic stereoselection. 25. Stereoselective synthesis of the C-1 to C-7 moiety of erythronolide A

Clayton H. Heathcock, Steven D. Young, James P. Hagen, Ronaldo Pilli, Ulrich Badertscher

J. Org. Chem. 1985, 50, 2095-2105

REACTION OF N-p-TOLUENESULFONYL DIPHENYLCYCLOPROPENIMINE WITH PYRIDINIUM N-IMINES

Albert Kascheres, José A. R. Rodrigues, Ronaldo A. Pilli

Heterocycles, 1984, 22, 1709-1711

Reaction of N-(p-tolylsulfonyl)diphenylcyclopropenimine with pyridinium and isoquinolinium ylides

Ronaldo Aloise Pilli, José A. R. Rodrigues, Albert Kascheres

J. Org. Chem. 1983, 48, 1084-1091